We have examined the insertion of carbenes carrying leaving groups into the [nido-B11H13]2− dianion to form the [closo-1-CB11H12]− anion. The best procedure uses CF3SiMe3 and LiCl as the source of CF2. It is simple, convenient and scalable and proceeds with 70–90% yield. Density functional calculations have been used to develop a mechanistic proposal that accounts for the different behavior of CF2, requiring only one equivalent of base for successful conversion of Na[nido-B11H14]− to [closo-1-CB11H12]−, and CCl2 and CBr2, which require more.
Molecules Videos: Download 53+ Free 4K & HD Stock Footage Clips
Molecules, Free Full-Text, chinese wall cpa 20
Cell-free translation of the globin message within polydisperse
Chemical Physics of Free Molecules
Molecules, Free Full-Text, kelly godoy coelho
Molecules, Free Full-Text, kelly godoy coelho
Molecules, Free Full-Text, kelly godoy coelho
Molecules Set of 4 Art PRINTABLES, Caffeine Happiness Sleep
Molecules, Free Full-Text, kelly godoy coelho
Molecular biology animated word cloud, t, Stock Video
What is a Molecule?, Molecules and Matter
New research area promotes both quantum computing and cognitive
Molecules Free Full-Text Research And Development Of, 59% OFF
Scientific Or Medical Background Water Molecules With Spacious
img./free-vector/set-model-3d-molecule