The simplest and best way to get rid of poison ivy is 'very carefully.'
The Complete Guide to Dealing with Poison Ivy, Oak, and Sumac
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Poison ivy rash - Diagnosis and treatment - Mayo Clinic
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What can I do to get rid of the poison ivy in my yard?
Be careful where you spray that stuff! - MSU Extension
How to Identify, Remove, and Treat Poison Sumac
How To Eliminate Poison Ivy! How To Kill Poison Ivy Safely & Naturally
How to Kill Poison Ivy in 5 Steps - Tenth Acre Farm